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Issue 3, 2001
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Nitrene-transfer to olefins catalyzed by methyltrioxorhenium: a universal catalyst for the [1+2] cycloaddition of C-, N-, and O-atom fragments to olefins

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Abstract

Methyltrioxorhenium (MTO) was found to catalyze the transfer of the nitrene unit of [N-(p-tolylsulfonyl)imino]- iodobenzene to a number of olefins providing aziridines in moderate to good yields, establishing MTO as a universal catalyst for the [1 + 2] cycloaddition of carbene, nitrene, and oxo units to olefins.

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Publication details

The article was received on 28 Sep 2000, accepted on 05 Dec 2000 and first published on 16 Jan 2001


Article type: Communication
DOI: 10.1039/B007906P
Citation: Chem. Commun., 2001,0, 235-236
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    Nitrene-transfer to olefins catalyzed by methyltrioxorhenium: a universal catalyst for the [1+2] cycloaddition of C-, N-, and O-atom fragments to olefins

    H. Jeon and S. T. Nguyen, Chem. Commun., 2001, 0, 235
    DOI: 10.1039/B007906P

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