Issue 3, 2001

Nitrene-transfer to olefins catalyzed by methyltrioxorhenium: a universal catalyst for the [1+2] cycloaddition of C-, N-, and O-atom fragments to olefins

Abstract

Methyltrioxorhenium (MTO) was found to catalyze the transfer of the nitrene unit of [N-(p-tolylsulfonyl)imino]- iodobenzene to a number of olefins providing aziridines in moderate to good yields, establishing MTO as a universal catalyst for the [1 + 2] cycloaddition of carbene, nitrene, and oxo units to olefins.

Article information

Article type
Communication
Submitted
28 Sep 2000
Accepted
05 Dec 2000
First published
16 Jan 2001

Chem. Commun., 2001, 235-236

Nitrene-transfer to olefins catalyzed by methyltrioxorhenium: a universal catalyst for the [1+2] cycloaddition of C-, N-, and O-atom fragments to olefins

H. Jeon and S. T. Nguyen, Chem. Commun., 2001, 235 DOI: 10.1039/B007906P

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