Issue 1, 2001

A comparison of the Cieplak model and the cation complexation model as applied to selected 2,3-disubstituted norbornan-7-ones

Abstract

Compared with the Cieplak model, which is totally inadequate for predicting the π-selectivities of 1a–1c, the antiperiplanar effects in suitably cation-complexed species predict carbonyl pyramidalizations that lead to the observed selectivities.

Supplementary files

Article information

Article type
Communication
Submitted
01 Nov 2000
Accepted
14 Nov 2000
First published
07 Dec 2000

J. Chem. Soc., Perkin Trans. 2, 2001, 1-2

A comparison of the Cieplak model and the cation complexation model as applied to selected 2,3-disubstituted norbornan-7-ones

V. K. Yadav and R. Balamurugan, J. Chem. Soc., Perkin Trans. 2, 2001, 1 DOI: 10.1039/B008808K

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