The solid- and solution-state structures of 2-nitrosopyridine and its 3- and 4-methyl derivatives
Abstract
values being in the range 53–58 kJ mol−1 and ΔG
‡ (298.15 K) values in the range 70–82 kJ mol−1. An X-ray crystal structure of 1 identified the compound as a Z-dimeric species with the two pyridine rings twisted by 62.7° and their heterocyclic N atoms pointing towards each other.