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Issue 17, 2000
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C-18 Hydroxylation of gibberellins

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Abstract

A protocol for the hydroxylation of the 18-methyl group in gibberellins has been developed, as demonstrated by the successful synthesis of 18-hydroxy GA4 methyl ester by means of a tandem process involving the conjugate addition of alkoxide to the α-methylene lactone moiety of a ring A-seco-gibberellin followed by an intramolecular aldol reaction.

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Publication details

The article was received on 26 Jul 2000, accepted on 02 Aug 2000 and first published on 14 Aug 2000


Article type: Communication
DOI: 10.1039/B006044P
Citation: J. Chem. Soc., Perkin Trans. 1, 2000,0, 2893-2894
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    C-18 Hydroxylation of gibberellins

    L. N. Mander and R. J. Thomson, J. Chem. Soc., Perkin Trans. 1, 2000, 0, 2893
    DOI: 10.1039/B006044P

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