Issue 10, 2000
From the journal:

New Journal of Chemistry

A novel heterobimetallic Ni(II)–Ag(I) cyano-bridged coordination polymer incorporating Ag···Ag interactions: {[Ni(cyclen)][Ag(CN)2]}[Ag(CN)2]

Iris P. Y. Shek,a   Wai-Yeung Wongb  and  Tai-Chu Lau*a  

* Corresponding authors

a Department of Biology and Chemistry, City Uniersity of Hong Kong, Tat Chee Aenue, Hong Kong, P.R. China
E-mail: bhtclau@cityu.edu.hk
Fax: Fax: +852 2788 7406

b Department of Chemistry, Hong Kong Baptist Uniersity, Waterloo Road, Kowloon Tong, P.R. China

Abstract

Reaction of nickel(II) acetate with cyclen (cyclen=1,4,7,10-tetraazacyclododecane) and K[Ag(CN)2] gave {[Ni(cyclen)][Ag(CN)2]}[Ag(CN)2], which consists of cis-[Ni(cyclen)]2+ units bridged by [Ag(CN)2]− to form a zig-zag chain; the Ag atoms of the free and bridging [Ag(CN)2]− also align together to form an infinite zig-zag chain with short Ag···Ag distances.

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B004939P
Article type
Letter
Submitted
19 Jun 2000
Accepted
02 Aug 2000
First published
15 Sep 2000

New J. Chem., 2000,24, 733-734

Permissions

Request permissions

A novel heterobimetallic Ni(II)–Ag(I) cyano-bridged coordination polymer incorporating Ag···Ag interactions: {[Ni(cyclen)][Ag(CN)2]}[Ag(CN)2]

I. P. Y. Shek, W. Wong and T. Lau, New J. Chem., 2000, 24, 733 DOI: 10.1039/B004939P

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements