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Issue 14, 2000
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Synthesis and structure of [Cp2PbCpthf<img border='0' src='http://www.rsc.org/images/entities/h2_char_200a.gif' alt=' '/>Na]·0.5thf; implications to the control of dimensionality in p block metallocene anion systems (Cp = C5H5, Cpthf = {C5H4}CH2C4H7O)

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Abstract

The title compound [Cp2PbCpthf Na]·0.5thf 1, obtained from the addition reaction of Cp2Pb with [Cpthf Na·thf], provides the first opportunity to assess the structural impact of internal donation on aggregation within a p block metal cyclopentadienide anion system; the result being the adoption of an unusual polymeric sheet structure composed of [Cp2PbCpthf Na]3 rings.

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Publication details

The article was received on 02 May 2000, accepted on 09 Jun 2000 and first published on 22 Jun 2000


Article type: Communication
DOI: 10.1039/B004608F
Citation: J. Chem. Soc., Dalton Trans., 2000, 2247-2248
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    Synthesis and structure of [Cp2PbCpthf<img border='0' src='http://www.rsc.org/images/entities/h2_char_200a.gif' alt=' '/>Na]·0.5thf; implications to the control of dimensionality in p block metallocene anion systems (Cp = C5H5, Cpthf = {C5H4}CH2C4H7O)

    N. Feeder, A. D. Hopkins, R. A. Layfield and D. S. Wright, J. Chem. Soc., Dalton Trans., 2000, 2247
    DOI: 10.1039/B004608F

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