Issue 20, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Four-co-ordinated copper(II) species obtained by X-ray irradiation of a three-co-ordinated copper(I) complex: a single crystal EPR study

Cornelia G. Palivan†*a  and  Sundara Ramaprabhub  

* Corresponding authors

a Department of Atomic and Nuclear Physics, Faculty of Physics, University of Bucharest, P.O. Box MG-11, Bucuresti-Magurele, Romania

b Department of Physics, Indian Institute of Technology, Madras, India

Abstract

X-Ray irradiation of a single crystal of chlorobis(1-isopropylimidazolidine-2-thione)copper(I) led to the formation of two copper(II) species whose structures were studied by EPR spectroscopy. The EPR parameters provide information on the structural changes which characterize the formation of the four-co-ordinated copper(II) species when the three-co-ordinated copper(I) precursor reacts with radiogenic radicals formed during the irradiation and provide insight into the reaction mechanism.

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Article information

DOI
https://doi.org/10.1039/B004294N
Article type
Paper
Submitted
31 May 2000
Accepted
21 Aug 2000
First published
22 Sep 2000

J. Chem. Soc., Dalton Trans., 2000, 3513-3518

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Four-co-ordinated copper(II) species obtained by X-ray irradiation of a three-co-ordinated copper(I) complex: a single crystal EPR study

C. G. Palivan and S. Ramaprabhu, J. Chem. Soc., Dalton Trans., 2000, 3513 DOI: 10.1039/B004294N

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