Issue 24, 2000

Enhanced electron phase-transfer catalysis due to the formation of substrate–catalyst inclusion complexes

Abstract

A redox-active macrocyclic ionene oligomer, cyclobis(paraquat-p-phenylene), exhibited an enhanced activity as an electron phase-transfer catalyst for the reduction of quinones compared with acyclic benzyl viologen, due to the inclusion of the substrate into the catalyst cavity.

Article information

Article type
Communication
Submitted
12 Sep 2000
Accepted
04 Oct 2000
First published
28 Nov 2000

Chem. Commun., 2000, 2455-2456

Enhanced electron phase-transfer catalysis due to the formation of substrate–catalyst inclusion complexes

H. Noguchi, H. Tsutsumi and M. Komiyama, Chem. Commun., 2000, 2455 DOI: 10.1039/B007404G

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