Configurationally stable metal-centered chirality:stereospecific and regioselective rhodaacylation of alkynes controlled bythe third generation of the [Cp′-P]H ligand

Yasutaka Kataoka; Yoko Iwato; Atsushi Shibahara; Tsuneaki Yamagata; Kazuhide Tani

doi:10.1039/B001735N

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Configurationally stable metal-centered chirality: stereospecific and regioselective rhodaacylation of alkynes controlled by the third generation of the [Cp′-P]H ligand

Yasutaka Kataoka,*^a Yoko Iwato,^a Atsushi Shibahara,^a Tsuneaki Yamagata^a and Kazuhide Tani*^a

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* Corresponding authors

^a Department of Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka, Japan.
E-mail: tani@chem.es.osaka-u.ac.jp

Abstract

The rhodium cationic complex [[η⁵∶η¹-{3-(NIM)Ind-P} _{n = 2}]Rh(CO)Me]BF₄ (1) reacts with 1-phenylpropyne regioselectively and stereospecifically to afford the alkenyl complex [[η⁵∶η¹-{3-(NIM)Ind-P} _{n =
2}]Rh{η²-O [double bond, length half m-dash] C(CH₃)- C(CH₃)CPh}]BF₄ (2).

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Supplementary files

Crystal data TXT (32K)

Article information

DOI: https://doi.org/10.1039/B001735N
Article type: Communication
Submitted: 03 Mar 2000
Accepted: 07 Apr 2000
First published: 03 May 2000

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Chem. Commun., 2000, 841-842

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Configurationally stable metal-centered chirality: stereospecific and regioselective rhodaacylation of alkynes controlled by the third generation of the [Cp′-P]H ligand

Y. Kataoka, Y. Iwato, A. Shibahara, T. Yamagata and K. Tani, Chem. Commun., 2000, 841 DOI: 10.1039/B001735N

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Chemical Communications

Configurationally stable metal-centered chirality: stereospecific and regioselective rhodaacylation of alkynes controlled by the third generation of the [Cp′-P]H ligand

Abstract

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Configurationally stable metal-centered chirality: stereospecific and regioselective rhodaacylation of alkynes controlled by the third generation of the [Cp′-P]H ligand

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