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Issue 8, 1999
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Total synthesis of the polyenoyltetramic acid mycotoxin erythroskyrine

Abstract

The first total synthesis of erythroskyrine, a polyenoyltetramic acid mycotoxin and principal pigment of Penicillium Islandicum Sopp., is described using a palladium(II) catalysed oxycarbonylation to create the furan-derived bicyclic portion 3 and the phosphonate ester 5 to furnish both the polyenoyl chain and the N-methyl(S )-valine derived tetramic acid terminus.

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Article type: Paper
DOI: 10.1039/A809823I
Citation: J. Chem. Soc., Perkin Trans. 1, 1999,0, 839-842
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    Total synthesis of the polyenoyltetramic acid mycotoxin erythroskyrine

    D. J. Dixon, S. V. Ley, T. Gracza and P. Szolcsanyi, J. Chem. Soc., Perkin Trans. 1, 1999, 0, 839
    DOI: 10.1039/A809823I

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