The intramolecular transesterification reaction of 2-hydroxypropyl 4-nitrophenyl phosphate is greatly accelerated (105–106 fold) by the addition of divalent metal ions such as Zn2+ and Cu2+ in MeCN without a base; the metal ion effect is quite sensitive to the content of H2O in MeCN.
S. Kondo, K. Yoshida and Y. Yano, J. Chem. Res. (S), 1999, 106 DOI: 10.1039/A803986K
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...