The solid-state structures of iron porphyrin hydroxamate complexes reveal an unusual monodentate η1-O binding mode; the bidentate η2-O,O binding of the tropolonate anion results in an apical displacement of iron of 0.80 Å from the 24-atom mean porphyrin plane.
L. Cheng, M. A. Khan, R. W. Taylor, G. B. Richter-Addo and D. R. Powell, Chem. Commun., 1999, 1941 DOI: 10.1039/A905485E
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