The catalytic, highly enantioselective hetero-Diels–Alder reactions of thiabutadienes using homochiral copper and nickel triflate and perchlorate bis(oxazoline) and bis(imine) complex catalysts to afford optically active dihydrothiopyrans are described for the first time.
T. Saito, K. Takekawa and T. Takahashi, Chem. Commun., 1999, 1001 DOI: 10.1039/A902076D
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