Issue 6, 1999

Lifting the lid on metatungstate. 1H and 183W NMR study of the six electron reduced anion [(H)2{WIV3(OH2)3}WVI9O34(OH)3]3–

Abstract

The distribution of the eleven protons present in a six-electron reduced form of metatungstate, [(H)2{WIV3- (OH2)3}WVI9O34(OH)3]3–, in dry CD3CN is mapped by 1H and 183W NMR, allowing assessment of structural changes which accompany reduction.

Article information

Article type
Paper

Chem. Commun., 1999, 533-534

Lifting the lid on metatungstate. 1H and 183W NMR study of the six electron reduced anion [(H)2{WIV3(OH2)3}WVI9O34(OH)3]3–

C. Boskovic, A. G. Wedd, M. Sadek, R. T. C. Brownlee and A. M. Bond, Chem. Commun., 1999, 533 DOI: 10.1039/A900088G

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