The first gold complex, [Se(AuPPh3)4](CF3SO3)2, with a µ4-selenido ligand has been prepared; the crystal structure reveals a square pyramidal geometry with short gold–gold interactions.
S. Canales, O. Crespo, M. Concepción Gimeno, A. Laguna and P. G. Jones, Chem. Commun., 1999, 679 DOI: 10.1039/A809739I
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