Protonation of a ruthenium hydride containing the hemilabile ligand PPh2py gave a complex with a three-centre dihydrogen bond (Ru–H···H–Py2), and this system exhibits a fast proton/hydride interchange and is a very active catalyst for D+–H2 exchange.
A. Caballero and F. A. Jalón, Chem. Commun., 1998, 1879 DOI: 10.1039/A803972K
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