Aluminium alkoxide moieties are grafted onto purely siliceous mesoporous MCM-41 via siloxide linkages, producing materials which reveal enhanced catalytic activity in the MPV reduction of cyclic ketones; nitrogen physisorption and 27Al MAS NMR spectroscopy are applied to characterise the catalytically active hybrid systems.
R. Anwander, G. Gerstberger, C. Palm, O. Groeger and G. Engelhardt, Chem. Commun., 1998, 1811 DOI: 10.1039/A802996B
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