SCHEDULED MAINTENANCE
PhMe2SiLi reacts with tertiary amides to give enediamines, which can be isolated in good yield when the α-carbon is branched; the enediamines can be hydrolysed more or less easily to α-amino ketones, isomerised from Z to E, oxidised to dienediamines and isomerised to amino enamines.
I. Fleming, U. Ghosh, S. R. Mack, I. Fleming, U. Ghosh, S. R. Mack and B. P. Clark, Chem. Commun., 1998, 711 DOI: 10.1039/A800648B
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