Issue 6, 1998

Dioxygenase-catalysed cis-dihydrodiol formation in the carbo- and hetero-cyclic rings of quinolines

Abstract

Evidence of enzyme-catalysed cis-dihydroxylation in the pyridine (3,4-bond) and benzene rings (5,6- and 7,8-bonds) of quinoline and 2-substituted quinolines is examined in light of the isolation of a heterocyclic cis-diol derivative of 2-quinolone, as a single enantiomer of opposite absolute configuration to that found for the enantiopure carbocyclic cis-diol metabolites from quinolines.

Article information

Article type
Paper

Chem. Commun., 1998, 683-684

Dioxygenase-catalysed cis-dihydrodiol formation in the carbo- and hetero-cyclic rings of quinolines

D. R. Boyd, N. D. Sharma, J. G. Carroll, J. F. Malone, D. G. Mackerracher, N. D. Sharma, J. G. Carroll, D. G. Mackerracher and C. C. R. Allen, Chem. Commun., 1998, 683 DOI: 10.1039/A709138I

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