Issue 3, 1998

Sulfinyl versus allylic stereocontrol in Diels–Alder cycloadditions of hydroxy 2-sulfinyl butadienes

Abstract

Enantiopure hydroxy 2-sulfinyl butadienes undergo a highly face selective Diels–Alder cycloaddition with N-phenylmaleimide and phenyltriazolinedione controlled by the chiral sulfur atom; the related enantiopure sulfonyl dienes display complimentary π-facial selectivity.

Article information

Article type
Paper

Chem. Commun., 1998, 409-410

Sulfinyl versus allylic stereocontrol in Diels–Alder cycloadditions of hydroxy 2-sulfinyl butadienes

R. Fernández de la Pradilla, C. Montero, R. Fernández de la Pradilla and A. Viso, Chem. Commun., 1998, 409 DOI: 10.1039/A708272J

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