A coordination network based on d0 transition-metal centers: synthesis and structure of the [2,4]-connected layered compound [(TiCl4)2Si(C6H4CN-p)4]·1.5C7H8
Abstract
The tetrafunctional silane Si(C6H4CN-p)4 forms a coordination network with TiCl4 consisting of 4,2-connected layers containing large (56 atom) rings.