Dynamic 1H NMR spectroscopy has been used to explore the influence of substituents on the internal rotation of the amino group in a series of twelve 2-(N,N-dialkylamino)chromones; the rotational barriers (ΔG‡) in CDCl3 and CD2Cl2 were found to range from 38 to 52 kJ mol-1.
P. T.Kaye Kaye and I. D. I. Ramaite, J. Chem. Res. (S), 1997, 414 DOI: 10.1039/A702801F
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...