Issue 15, 1997

Diastereoselective intramolecular photochemical [2 + 2] cycloaddition reactions of tethered l-(+)-valinol derived tetrahydrophthalimides

Abstract

Intramolecular photochemical [2 + 2] cycloaddition of allyl alcohol linked to amino acid derived 3,4,5,6-tetrahydrophthalimides, either via a carbonate or silicon tether, gives the corresponding cyclobutanes in excellent yield with diastereoselectivities as high as 8:1.

Article information

Article type
Paper

Chem. Commun., 1997, 1385-1386

Diastereoselective intramolecular photochemical [2 + 2] cycloaddition reactions of tethered l-(+)-valinol derived tetrahydrophthalimides

K. I. Booker-Milburn, S. Gulten and A. Sharpe, Chem. Commun., 1997, 1385 DOI: 10.1039/A702386C

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