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Issue 6, 1997
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Asymmetric catalytic intramolecular hydroacylation of 4-substitutedpent-4-enals to β-substituted cyclopentanones

Abstract

The catalyst, [Rh(S,S-Me-duphos)(acetone) 2 ] + , rapidly and efficiently converts 4-substituted pent-4-enals bearing primary and secondary substituents to the corresponding cyclopentanones and for a variety of substituents the ee was found to range from 93 to 96% at 25 °C.

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Article type: Paper
DOI: 10.1039/A700076F
Citation: Chem. Commun., 1997,0, 589-590
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    Asymmetric catalytic intramolecular hydroacylation of 4-substituted pent-4-enals to β-substituted cyclopentanones

    R. W. Barnhart, D. A. McMorran and B. Bosnich, Chem. Commun., 1997, 0, 589
    DOI: 10.1039/A700076F

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