Preparation of seven and larger membered heterocycles by electrophilic heteroatom cyclization

Gérard Rousseau; Fadi Homsi

doi:10.1039/CS9972600453

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Chemical Society Reviews

Issue 6, 1997

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Preparation of seven and larger membered heterocycles by electrophilic heteroatom cyclization

Gérard Rousseau and Fadi Homsi

Chem. Soc. Rev., 1997,26, 453-461

DOI: 10.1039/CS9972600453

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The preparation of seven and larger membered ring compounds from linear substrates is known to be a difficult process. We report results for the preparation of heterocycles with these ring sizes by electrophilic heteroatom cyclizations. Examination of the literature shows that the obtention of seven-membered compounds is possible in good yields by a proper choice of the electrophilic reagents, while for eight and larger membered compounds these cyclisations are possible only if steric constraints are introduced into the chain.

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Preparation of seven and larger membered heterocycles by electrophilic heteroatom cyclization

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