Issue 13, 1997
From the journal:

Chemical Communications

Hypervalent iodine-induced oxidative nucleophilic additions to alkenes: a novel acetoxy thiocyanation reaction in 1,1,1,3,3,3-hexafluoropropan-2-ol

Antonella De Mico,   Roberto Margarita,   Andrea Mariani  and  Giovanni Piancatelli  

Abstract

The combination of [bis(acetoxy)iodo]benzene and thiocyanate anion in a polar, protic non nucleophilic solvent such as 1,1,1,3,3,3-hexafluoropropan-2-ol is able to perform an oxidative nucleophilic addition to alkenes, leading to acetoxy thiocyanate derivatives, stereoselectively and with good regioselectivity.

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Article information

DOI
https://doi.org/10.1039/A701998J
Article type
Paper

Chem. Commun., 1997, 1237-1238

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Hypervalent iodine-induced oxidative nucleophilic additions to alkenes: a novel acetoxy thiocyanation reaction in 1,1,1,3,3,3-hexafluoropropan-2-ol

A. De Mico, R. Margarita, A. Mariani and G. Piancatelli, Chem. Commun., 1997, 1237 DOI: 10.1039/A701998J

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