Preparations and structures of a series of novel, mono-substituted cis,cis-1,3,5-triaminocyclohexane-based complexes
Abstract
The complexation of triimine ligands based on cis,cis-1,3,5-triaminocyclohexane with copper salts caused a selective hydrolysis reaction producing new monoimine complexes, the single-crystal structures of which showed the ligand skeletons to be isostructural, with a well defined rigid superstructure adjacent to the metal centre.