Issue 22, 1996

Iron(III)-mediated oxidative cyclisations of cyclopropanone acetals

Abstract

Treatment of the cyclopropanone acetals 7 or 11 with three different FeIII species gives the lactone 9 and the ester 13 respectively via an oxidative cyclopropane cleavage followed by a 5-exo radical cyclisation–abstraction sequence.

Article information

Article type
Paper

Chem. Commun., 1996, 2577-2578

Iron(III)-mediated oxidative cyclisations of cyclopropanone acetals

K. I. Booker-Milburn, B. Cox and T. E. Mansley, Chem. Commun., 1996, 2577 DOI: 10.1039/CC9960002577

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