Issue 21, 1996
From the journal:

Chemical Communications

Samarium-mediated redistribution of silanes and formation of trinuclear samarium–silicon clusters

Nora S. Radu,   Frederick J. Hollander,   T. Don Tilley  and  Arnold L. Rheingold  

Abstract

The samarium complex Cp*2SmCH(SiMe3)2(Cp*= C5Me5), unlike the related alkyls Cp*2LnCH(SiMe3)3(Ln = Y, Nd), mediates the redistribution of hydrosilanes while being converted to trisamarium clusters, including Cp*6Sm3(µ-SiH3)(µ3-η1,η1,η2-SiH2-SiH2).

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Article information

DOI
https://doi.org/10.1039/CC9960002459
Article type
Paper

Chem. Commun., 1996, 2459-2460

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Samarium-mediated redistribution of silanes and formation of trinuclear samarium–silicon clusters

N. S. Radu, F. J. Hollander, T. D. Tilley and A. L. Rheingold, Chem. Commun., 1996, 2459 DOI: 10.1039/CC9960002459

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