Addition of conjugated diene to an equimolar mixture of palladium(II) halides and a palladium(0) complex induces facile Pd–Pd bond formation to give anionic, neutral and cationic PdI-PdI dinuclear complexes containing bridging 1,3-diene ligands.
T. Murahashi, N. Kanehisa, Y. Kai, T. Otani and H. Kurosawa, Chem. Commun., 1996, 825 DOI: 10.1039/CC9960000825
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