Issue 9, 1995

Cyclopenta[b]indoles. Part 2. Model studies towards the tremorgenic mycotoxins

Abstract

The 7-bromocyclopenta[b]indole 3 has been converted into the hydroxybutenyl derivatives 5 and 6, and the tetrahydrofuranylidene derivative 8 in model studies towards the elaboration of paspalitrem and lolitrem type side chains. In a parallel approach, the cyclopentapyrrole 13 was converted into the fused α-pyrone 16 which acted as a pyrrole-2,3-quinodimethane, and underwent Diels–Alder reaction to give, after loss of carbon dioxide, the cyclopentaindoles 1721.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1995, 1131-1136

Cyclopenta[b]indoles. Part 2. Model studies towards the tremorgenic mycotoxins

C. Harrison, P. M. Jackson, C. J. Moody and J. M. J. Williams, J. Chem. Soc., Perkin Trans. 1, 1995, 1131 DOI: 10.1039/P19950001131

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