The reaction of [Fe{o-(CH2)2C6H4}(CO)3]1 with o-LiC6H4CH2NMe2, in Et2O at low temperature, followed by alkylation of the acylmetallate intermediate formed with [Et3O]BF4 in aqueous solution at 0 °C gives a novel chelated isomerized carbene complex [[graphic omitted]H2}(CO)3]2 whose structure is established by X-ray crystallography.
Y. Yu, J. Chen, J. Chen and P. Zheng, J. Chem. Soc., Chem. Commun., 1995, 2089 DOI: 10.1039/C39950002089
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