Issue 17, 1995

Metal-assisted activation of the C–O bond of 2-hydroxyethylmethacrylate. Synthesis and molecular structure of Ti5(OPri)9(µ-OPri)(µ,η2-OC2H4O)(µ32-OC2H4O)342-OC2H4O)

Abstract

Ti5(OPri)9(µ-OPri)(OC2H4O)5 is formed by the reaction between Ti(OPri)4 and 2-hydroxyethylmethacrylate in toluene at room temperature; the pentanuclear aggregate is asymmetric with the titanium atoms displaying coordination numbers of five, six and seven.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1817-1819

Metal-assisted activation of the C–O bond of 2-hydroxyethylmethacrylate. Synthesis and molecular structure of Ti5(OPri)9(µ-OPri)(µ,η2-OC2H4O)(µ32-OC2H4O)342-OC2H4O)

N. Pajot, R. Papiernik, L. G. Hubert-Pfalzgraf, J. Vaissermann and S. Parraud, J. Chem. Soc., Chem. Commun., 1995, 1817 DOI: 10.1039/C39950001817

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