The efficacy of various solid acid catalysts and exchanged clays in a single-pot synthesis of methyl tert-butyl ether (MTBE) from tert-butyl alcohol and methanol is investigated; dodecatungstophosphoric acid (HPA) supported on K-10 clay gives the best yield with highest selectivity for MTBE.
G. D. Yadav and N. Kirthivasan, J. Chem. Soc., Chem. Commun., 1995, 203 DOI: 10.1039/C39950000203
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