Issue 24, 1994

Synthesis of 1-arylalk-2-enes and 1-arylalkanes via Friedel–Crafts alkylation with allylic alcohols catalysed by an acidic clay

Abstract

Moderately activated benzenoid compounds undergo alkylation with allylic alcohols in the presence of acidic K10 clay to give almost exclusively 1-arylalk-2-enes by attack at the terminal position of the intermediate allyl cation; catalytic hydrogenation yields the corresponding 1-arylalkanes.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1994, 3519-3520

Synthesis of 1-arylalk-2-enes and 1-arylalkanes via Friedel–Crafts alkylation with allylic alcohols catalysed by an acidic clay

K. Smith and G. M. Pollaud, J. Chem. Soc., Perkin Trans. 1, 1994, 3519 DOI: 10.1039/P19940003519

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