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Issue 17, 1994
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A novel one-pot synthesis of homochiral (R)-(–)- and (S)-(+)- Fe(CO)(η5-C5H5)(PPh3)COCH3

Abstract

Treatment of the salt [Fe(CO)25-C5H5)(PPh3)]Br with potassium L-mentholate followed by lithium bromide and methyllithium generates, after work-up and crystallisation, homochiral (S)-(+)-[Fe(CO)(η5-C5H5)(PPh3)COCH3] in [gt-or-equal] 30% yield.

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Article type: Paper
DOI: 10.1039/P19940002369
Citation: J. Chem. Soc., Perkin Trans. 1, 1994,0, 2369-2372
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    A novel one-pot synthesis of homochiral (R)-(–)- and (S)-(+)- Fe(CO)(η5-C5H5)(PPh3)COCH3

    S. J. Cook, J. F. Costello, S. G. Davies and H. T. Kruk, J. Chem. Soc., Perkin Trans. 1, 1994, 0, 2369
    DOI: 10.1039/P19940002369

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