The synthesis and single crystal X-ray structures are reported of two interwoven cationic frameworks that are based upon tetrahedral and trigonal CuI ions; the resulting architectures are diamondoid, [CuI(bipy)2(PF6)]∞(bipy = 4,4′-bipyridyl)1, and honeycomb, [CuI)2(pz)3(SiF6)]∞(pz = pyrazine)2, respectively.
L. R. MacGillivray, S. Subramanian and M. J. Zaworotko, J. Chem. Soc., Chem. Commun., 1994, 1325 DOI: 10.1039/C39940001325
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