Issue 1, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Reversible thermal carbon–hydrogen bond cleavage in alkanes and arenes with dihalogenobis(triphenylphosphine)palladium(II) complexes

Andrei N. Vedernikov,   Arkadii I. Kuramshin  and  Boris N. Solomonov  

Abstract

Dihalogenobis(triphenylphosphine)palladium(II) complexes 1, PdX2(PPh3)2(X = Cl, Br, I), reacts reversibly with saturated and aromatic hydrocarbons RH (RH =p-xylene, toluene, benzene, n-hexane, cyclohexane), slowly at ambient temperature and rapidly on heating at 70–130 °C, to produce hydridodihalogeno(organo)bis(triphenylphosphine)-palladium(IV) complexes 2, Pd(H)(R)X2(PPh3)2; in the presence of bases complexes 2 eliminate hydrogen halide forming organobis(triphenylphosphine)palladium(II) halide 3, Pd(R)X(PPh3)2.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39940000121
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 121-122

Permissions

Request permissions

Reversible thermal carbon–hydrogen bond cleavage in alkanes and arenes with dihalogenobis(triphenylphosphine)palladium(II) complexes

A. N. Vedernikov, A. I. Kuramshin and B. N. Solomonov, J. Chem. Soc., Chem. Commun., 1994, 121 DOI: 10.1039/C39940000121

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements