Issue 23, 1994

Sulfur dioxide insertion reactions into metal–alkoxide bonds: synthesis and crystal structure of catena-bis(methylsulfito)bis(methanol)calcium; a one-dimensional polymer based on eight-coordinate calcium ions

Abstract

The reaction of So2(g) with a suspension of [M(OMe)2]n(M = Mg and Ca) in methanol yields the crystalline compounds, [M(O2SOMe)2(MeOH)2](M = Mg 1, Ca 2); the insertion reaction is of high yield and the X-ray crystal structure of complex 2 reveals that it is a chain polymer with eight-coordinated CaII ions and the methylsulfito anions acting as both chelating and bridging ligands.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 2695-2696

Sulfur dioxide insertion reactions into metal–alkoxide bonds: synthesis and crystal structure of catena-bis(methylsulfito)bis(methanol)calcium; a one-dimensional polymer based on eight-coordinate calcium ions

V. Arunasalam, I. Baxter, M. B. Hursthouse, K. M. A. Malik, D. M. P. Mingos and J. C. Plakatouras, J. Chem. Soc., Chem. Commun., 1994, 2695 DOI: 10.1039/C39940002695

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