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Issue 9, 1993
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Photofragmentation voltammetry studies of the aminocarbene complexes [(η5-C5H5)Fe(CO)(L){[double bond, length half m-dash]C(NHR1)(R2)}]BF4[L = PPh3, P(p-Tol)3; R1= Me, CH2Ph; R2= Me, Bu]

Abstract

The synthesis of the complexes [(η5-C5H5)Fe(CO)(L){[double bond, length half m-dash]C(NHR1)(R2)}]BF4[L = PPh3, P(p-Tol)3; R1= Me, CH2Ph; R2= Me, Bu] is described. Photofragmentation voltammetry is used to demonstrate that the primary photoprocess is loss of the phosphine ligand in all four carbene complexes. A common intermediate is observed when the analogous aminocarbenes are studied.

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Article type: Paper
DOI: 10.1039/P29930001603
Citation: J. Chem. Soc., Perkin Trans. 2, 1993,0, 1603-1609
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    Photofragmentation voltammetry studies of the aminocarbene complexes [(η5-C5H5)Fe(CO)(L){[double bond, length half m-dash]C(NHR1)(R2)}]BF4[L = PPh3, P(p-Tol)3; R1= Me, CH2Ph; R2= Me, Bu]

    S. G. Davies, M. R. Metzler, W. C. Watkins, R. G. Compton, J. Booth and J. C. Eklund, J. Chem. Soc., Perkin Trans. 2, 1993, 0, 1603
    DOI: 10.1039/P29930001603

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