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Issue 1, 1993
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Organometallic photoelectrochemistry: the photo-oxidation of an (arene)chromium tricarbonyl system

Abstract

The photoelectrochemical oxidation of the compound tricarbonyl(N,N,N′,N′-tetramethyl-1,4- phenylenediamine)chromium 1, has been studied using a platinum channel electrode. Maximum photocurrents are seen at an irradiation wavelength of 365 nm corresponding to a metal-to-ligand charge transfer absorption. By means of in situ electrochemical EPR and quantitative photocurrent/mass transport measurements the process is shown to be of the photo-CE type and a rate constant and approximate quantum yield are reported.

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Article type: Paper
DOI: 10.1039/P29930000039
Citation: J. Chem. Soc., Perkin Trans. 2, 1993,0, 39-42
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    Organometallic photoelectrochemistry: the photo-oxidation of an (arene)chromium tricarbonyl system

    R. G. Compton, R. Barghout, J. C. Eklund, A. C. Fisher, S. G. Davies and M. R. Metzler, J. Chem. Soc., Perkin Trans. 2, 1993, 0, 39
    DOI: 10.1039/P29930000039

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