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Issue 17, 1993
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Michael reaction of functionalized chiral cyclanone imines. Enantioselective synthesis of C2-symmetric cis-(1R,6R)-1,6-dimethylbicyclo[4.4.0]decane-3,8-dione

Abstract

Enantioselective Michael reaction of methyl acrylate or methyl vinyl ketone with a chiral imine of 2-methylcyclohexanone having a protected carbonyl function in the 4-position 2 led to monoprotected keto ester 4 or dione 6. The latter was converted into the title compound 10.

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Article type: Paper
DOI: 10.1039/P19930001935
Citation: J. Chem. Soc., Perkin Trans. 1, 1993,0, 1935-1936
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    Michael reaction of functionalized chiral cyclanone imines. Enantioselective synthesis of C2-symmetric cis-(1R,6R)-1,6-dimethylbicyclo[4.4.0]decane-3,8-dione

    M. Pfau, I. Jabin and G. Revial, J. Chem. Soc., Perkin Trans. 1, 1993, 0, 1935
    DOI: 10.1039/P19930001935

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