Issue 21, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

Kinetic resolution of the chiral iron acetyl [Fe(η5-C5H5)(CO)(PPh3)COMe]

Stephen C. Case-Green,   James F. Costello,   Stephen G. Davies,   Nicholas Heaton,   Charles J. R. Hedgecock  and  Jeremy C. Prime  

Abstract

The chiral discrimination displayed between the enolate derived from (RS)-[Fe(η5-C5H5)(CO)(PPh3)COMe] and (1R)-(+)-camphor furnishes a practical route to homochiral (R)-[Fe(η5-C5H5)(CO)(PPh3)COMe]via a kinetic resolution protocol, while a retro-aldol reaction of the diastereoisomerically pure aldol addition product of this kinetic resolution sequence provides a complementary route to the opposite enantiomer (S)-[Fe(η5-C5H5)(CO)(PPh3)COMe].

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Article information

DOI
https://doi.org/10.1039/C39930001621
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1621-1622

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Kinetic resolution of the chiral iron acetyl [Fe(η5-C5H5)(CO)(PPh3)COMe]

S. C. Case-Green, J. F. Costello, S. G. Davies, N. Heaton, C. J. R. Hedgecock and J. C. Prime, J. Chem. Soc., Chem. Commun., 1993, 1621 DOI: 10.1039/C39930001621

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