Issue 1, 1993

Acetylenic derivatives of [Fe2(CO)6(µ-Se2)]: acetylenic bond reduction on a selenium-stabilised Fe2Pt mixed-metal complex

Abstract

Stepwise addition of phenylacetylene and Pt(PPh3)2across the Se–Se bond of [Fe2(CO)6(µ-Se2)] can be carried out at room temperature; X-ray analysis demonstrates the acetylenic carbon–carbon bond reduction in the mixed-metal complex [(CO)6Fe2Pt(PPh3)2{µ-SeC(Ph)C(H)Se}].

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 46-48

Acetylenic derivatives of [Fe2(CO)6(µ-Se2)]: acetylenic bond reduction on a selenium-stabilised Fe2Pt mixed-metal complex

P. Mathur, M. Hossain, K. Das and U. C. Sinha, J. Chem. Soc., Chem. Commun., 1993, 46 DOI: 10.1039/C39930000046

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