Issue 7, 1992
From the journal:

Journal of the Chemical Society, Dalton Transactions

Carboxylate bridging of amino acids in dinuclear macrocyclic nickel(II) complexes

Ramprasad Das,   Kausik K. Nanda,   K. Venkatsubramanian,   Parimal Paul  and  Kamalaksha Nag  

Abstract

The dinuclear nickel(II) complex [Ni2L(MeOH)2(ClO4)2]·2NEt3HClO4, derived from a tetraazadiphenol macrocyclic ligand H2L, on reaction with glycine, β-alanine and glycylglycine affords the µ-carboxylato complexes of composition [Ni2L(–O2C–NH3+)(H2O)2][ClO4]2·nH2O. The structure of [Ni2L(µ-O2CCH2NH3)(H2O)2][ClO4]2·2H2O has been determined: monoclinic, space group Cc, with a= 17.465(2), b= 21.834(2), c= 11.480(1)Å, β= 115.27(2)° and Z= 4. The structure was solved by direct methods and refined to R= 0.047 and R′= 0.064.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9920001253
Article type
Paper

J. Chem. Soc., Dalton Trans., 1992, 1253-1257

Permissions

Request permissions

Carboxylate bridging of amino acids in dinuclear macrocyclic nickel(II) complexes

R. Das, K. K. Nanda, K. Venkatsubramanian, P. Paul and K. Nag, J. Chem. Soc., Dalton Trans., 1992, 1253 DOI: 10.1039/DT9920001253

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements