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Issue 3, 1991
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Preparation of tricarbonyl(η6-pyridine)chromium(0) complexes

Abstract

The synthesis of tricarbonyl(η6-pyridine)chromium(0) complexes is accomplished via complexation of 2-silylpyridines with subsequent fluoride ion-mediated desilylation under mild conditions. The tricarbonylchromium(0) complexes of pyridine, 2-methylpyridine, 3-methylpyridine, 2-ethylpyridine, 2-(but-3-enyl)pyridine and 2-(6-trimethylsilylpyridyl)-1,3-dioxolane are prepared. Deprotonation (lithium diisopropylamide) and methylation (methyl iodide) of tricarbonyl(η6-pyridine) chromium (0) converts it cleanly into tricarbonyl(η6-2-methylpyridine)chromium (o).

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Article type: Paper
DOI: 10.1039/P19910000501
Citation: J. Chem. Soc., Perkin Trans. 1, 1991,0, 501-507
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    Preparation of tricarbonyl(η6-pyridine)chromium(0) complexes

    S. G. Davies and M. R. Shipton, J. Chem. Soc., Perkin Trans. 1, 1991, 0, 501
    DOI: 10.1039/P19910000501

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