Issue 10, 1991
From the journal:

Journal of the Chemical Society, Dalton Transactions

Preparation and characterization of two isocyanide derivatives of monosubstituted [Fe3(CO)9S2]; crystal structure of [Fe3(CO)8(CNPh)(µ2-S)2]

Helgard G. Raubenheimer,   Lorna Linford,   Gert Kruger  and  Anthonie Lombard  

Abstract

Irradiation of [Fe(CO)5] in the presence of PhNCS produced [Fe3(CO)9(µ3-S)2] and two isomeric phenyl isocyanide derivatives, [Fe3(CO)8(CNPh)(µ3-S)2], substituted on either a central or a terminal iron atom. The crystal structure of the centrally substituted isomer was determined by X-ray diffraction.

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Article information

DOI
https://doi.org/10.1039/DT9910002795
Article type
Paper

J. Chem. Soc., Dalton Trans., 1991, 2795-2797

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Preparation and characterization of two isocyanide derivatives of monosubstituted [Fe3(CO)9S2]; crystal structure of [Fe3(CO)8(CNPh)(µ2-S)2]

H. G. Raubenheimer, L. Linford, G. Kruger and A. Lombard, J. Chem. Soc., Dalton Trans., 1991, 2795 DOI: 10.1039/DT9910002795

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