A general synthetic route to fully N-alkylated azamacrocycles, and an uncommon geometry for a six-coordinate nickel(II) complex of 1,4,8,11-tetrapropyl-1,4,8,11-tetraazacyclotetradecane (L1). Crystal structure of trans-(R,S,R,S)-[Ni(L1)(NCS)2]

Nathaniel W. Alcock; Andrew C. Benniston; Simon J. Grant; Hadi A. A. Omar; Peter Moore

doi:10.1039/C39910001573

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A general synthetic route to fully N-alkylated azamacrocycles, and an uncommon geometry for a six-coordinate nickel(II) complex of 1,4,8,11-tetrapropyl-1,4,8,11-tetraazacyclotetradecane (L¹). Crystal structure of trans-(R,S,R,S)-[Ni(L¹)(NCS)₂]

Nathaniel W. Alcock, Andrew C. Benniston, Simon J. Grant, Hadi A. A. Omar and Peter Moore

Abstract

A two-step route to a range of fully N-alkylated azamacrocycles has been developed; the crystal structure of trans-[Ni(L¹)(NCS)₂](L¹= 1,4,8,11-tetrapropyl-1,4,8,11-tetraazacyclotetradecane) shows the nickel(II) to be six-coordinate, but with the uncommon (R,S,R,S)-or trans-(I)-set of N-configurations.

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DOI: https://doi.org/10.1039/C39910001573
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1991, 1573-1575

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A general synthetic route to fully N-alkylated azamacrocycles, and an uncommon geometry for a six-coordinate nickel(II) complex of 1,4,8,11-tetrapropyl-1,4,8,11-tetraazacyclotetradecane (L¹). Crystal structure of trans-(R,S,R,S)-[Ni(L¹)(NCS)₂]

N. W. Alcock, A. C. Benniston, S. J. Grant, H. A. A. Omar and P. Moore, J. Chem. Soc., Chem. Commun., 1991, 1573 DOI: 10.1039/C39910001573

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Journal of the Chemical Society, Chemical Communications

A general synthetic route to fully N-alkylated azamacrocycles, and an uncommon geometry for a six-coordinate nickel(II) complex of 1,4,8,11-tetrapropyl-1,4,8,11-tetraazacyclotetradecane (L¹). Crystal structure of trans-(R,S,R,S)-[Ni(L¹)(NCS)₂]

Abstract

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A general synthetic route to fully N-alkylated azamacrocycles, and an uncommon geometry for a six-coordinate nickel(II) complex of 1,4,8,11-tetrapropyl-1,4,8,11-tetraazacyclotetradecane (L¹). Crystal structure of trans-(R,S,R,S)-[Ni(L¹)(NCS)₂]

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