SCHEDULED MAINTENANCE
The symmetrically H-bridged structure of the cyclooctyl cation is confirmed definitively by the characteristic IR vibration at 1845 cm–1 and by the agreement of the IGLO chemical shifts calculated with MP2/6-31G* geometry of the chair–boat (CS) conformation with the experimental NMR values.
P. Buzek, P. von Ragué Schleyer, H. Vančik and D. E. Sunko, J. Chem. Soc., Chem. Commun., 1991, 1538 DOI: 10.1039/C39910001538
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