SCHEDULED MAINTENANCE
Addition of thiyl radicals to alkynes produces vinyl radicals that abstract hydrogen atoms from tetrahydrofurans and a tetrahydropyran mimicking the crucial stages of the action of the anti-tumour agents, neocarzinostatin, esperamicin and calicheamicin.
J. Griffiths and J. A. Murphy, J. Chem. Soc., Chem. Commun., 1991, 1422 DOI: 10.1039/C39910001422
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